3月14日下午，应化学化工学院、生态环境相关高分子材料教育部重点实验室、甘肃省高分子材料重点实验室、甘肃省生物电化学与环境分析重点实验室和甘肃省电化学技术与纳米器件工程实验室的邀请，中科院“百人计划”入选者、中科院兰州化物所夏纪宝研究员到我院进行学术交流，并作了题为“sp3碳-氢氧化氟化反应研究”的学术报告。化工学院100余人参加了报告会。

    报告中，夏纪宝研究员结合自己的研究工作对钒催化C(sp3)-H的高选择性氧化、氟化反应和可见光促进有机催化的C(sp3)-H氟化反应作了系统深入的介绍。尤其对光促进有机催化的C(sp3)-H氟化反应进行了详细的讲解，引起了与会师生的浓厚兴趣，报告结束后，夏纪宝研究员与参会的老师和研究生就该领域相关问题进行了交流讨论。

【报告人简介】

         夏纪宝，研究员，博士生导师，中科院“百人计划”， 2010年 中科院上海有机化学研究所博士毕业， 2010.9 – 2015.3 在得州大学西南医学中心做博士后工作，2015.3 – 中科院兰州化学物理研究所，研究员  J. Am. Chem. Soc.、Chem. Commun、ChemCatChem等国际著名期刊发表多篇学术论文。

一、荣誉奖励

2010上海有机所GSK 奖学金

2015中科院“百人计划”A类

二、代表论著

17. Zhu, D.-Y.; Chen, P.; Xia, J.-B. “Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C–H Activation” ChemCatChem, 2016, 8, 68-73.

16. Xia, J.-B.; You, S.-L. „„C–C Bond Formation byDouble C–H Bond Activation‟‟, in Science of Synthesis, Yu, J.-Q., Ed, Thieme, Stuttgart, 2015, 115-136.

15. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free sp3-C–H Fluorination” Chem. Commun. 2014, 50, 11701-11704.

14. Xia, J.-B.; Ma, Y.; Chen, C. “Vanadium-Catalyzed C(sp3)–H Fluorination Reactions” Org. Chem. Front. 2014, 1, 468-472.

13. Zhu, C.; Xia, J.-B.; Chen, C. “A Simple Method for the Electrophilic Cyanation of Secondary Amines” Org. Lett. 2014, 16, 247-250.

12. Zhu, C.; Xia, J.-B.; Chen, C. “Vanadium-Catalyzed Oxidative Strecker Reaction: α-C–H Cyanation of para-Methoxyphenyl (PMP)-Protected Primary Amines” Tetrahedron Lett.2014, 55, 232-234.

11. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination” J. Am. Chem. Soc.2013, 135, 17494-17500. Highlighted in Synfacts 2014, 10, 85.

10. Xia, J.-B.; Cormier, W. K.; Chen, C. “A Highly Selective Vanadium Catalyst forBenzylic C–H Oxidation” Chem. Sci.2012, 3, 2240-2245.

9. Liu, W.-B.; Xia, J.-B.; You, S.-L. “Iridium-Catalyzed Asymmetirc Allylic Substitutions” Top. Organomet. Chem. 2012, 38, 155-208.

8. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L. “Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptanes and 3-Azabicyclo[3.2.0]heptanes viaIr-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction” Chem. Eur. J.2010, 16, 6442-6446. Highlighted in Synfacts 2010, 8, 909.

7. You, S.-L.; Xia, J.-B.; „.Palladium-Catalyzed Aryl–Aryl Bond Formation through Double C–H Activation‟. Top. Curr. Chem. 2010, 292, 165-194.

6. Xia, J.-B.; Jamison, T. F.; You, S.-L. „.Monodentate Chiral Ferrocenyl Ligands‟., in Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications, Dai, L.-X., Hou, X.-L., Eds, WILEY-VCH, Weinheim, 2010, pp. 55-71.

5. Xia, J.-B.; Zhuo, C.-X.; You, S.-L. “Synthesis of Cyclopropane-containing Building Blocks viaIr-Catalyzed Enantioselective Allylic Substitution Reaction” Chin. J. Chem. 2010, 28, 1525-1528.

4. Xia, J.-B.; You, S.-L. „.Synthesis of 3-Haloindolizines by Copper(II) Halides Mediated Direct Functionalization of Indolizines‟. Org. Lett. 2009, 11, 1187-1190.

3. Xia, J.-B.; Wang, X.-Q.; You, S.-L.„.Synthesis of Biindolizines through Highly Regioselective Palladium-Catalyzed C–H Functionalization‟. J. Org. Chem. 2009, 74, 456-458.

2. Wang, X.-Q.; Xia, J.-B.; Dai, X.-Y.; You, S.-L.„.Preparation of Ferrocenyl Imidazolines using Bis(triphenyl)oxodiphosphonium Trifluoromethansulfonate” Sci. China Chem.2009, 52,1331-1336.

1. Xia, J.-B.; You, S.-L.„.Carbon–CarbonBond Formation through Double sp2 C–H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives‟. Organometallics 2007, 26, 4869-4871.