报告题目：sp3碳-氢氧化氟化反应研究

报告人：夏纪宝  研究员、博导

       中科院“百人计划”研究员

报告人单位：中科院兰州化学物理研究所，羰基合成与选择氧化国家重点实验室，

报告时间：2017年3月14日（星期二）15:00

报告地点：新校区303多媒体教室

组织单位：化学化工学院   科技处

生态环境相关高分子材料教育部重点实验室

甘肃省高分子材料重点实验室

甘肃省生物电化学与环境分析重点实验室

甘肃省电化学技术与纳米器件工程实验室

夏纪宝研究员简介：

夏纪宝，研究员，博士生导师，中科院“百人计划”， 2010年 中科院上海有机化学研究所博士毕业， 2010.9 – 2015.3 在得州大学西南医学中心做博士后工作，2015.3 – 中科院兰州化学物理研究所，研究员  J. Am. Chem. Soc.、Chem. Commun、ChemCatChem等国际著名期刊发表多篇学术论文

 一、 荣誉奖励

2010上海有机所GSK 奖学金

2015中科院“百人计划”A类

二、代表论著

17. Zhu, D.-Y.; Chen, P.; Xia, J.-B. “Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C–H Activation” ChemCatChem, 2016, 8, 68-73.

16. Xia, J.-B.; You, S.-L. „„C–C Bond Formation byDouble C–H Bond Activation‟‟, in Science of Synthesis, Yu, J.-Q., Ed, Thieme, Stuttgart, 2015, 115-136.

15. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free sp3-C–H Fluorination” Chem. Commun. 2014, 50, 11701-11704.

14. Xia, J.-B.; Ma, Y.; Chen, C. “Vanadium-Catalyzed C(sp3)–H Fluorination Reactions” Org. Chem. Front. 2014, 1, 468-472.

13. Zhu, C.; Xia, J.-B.; Chen, C. “A Simple Method for the Electrophilic Cyanation of Secondary Amines” Org. Lett. 2014, 16, 247-250.

12. Zhu, C.; Xia, J.-B.; Chen, C. “Vanadium-Catalyzed Oxidative Strecker Reaction: α-C–H Cyanation of para-Methoxyphenyl (PMP)-Protected Primary Amines” Tetrahedron Lett.2014, 55, 232-234.

11. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination” J. Am. Chem. Soc.2013, 135, 17494-17500.

 Highlighted in Synfacts 2014, 10, 85.

10. Xia, J.-B.; Cormier, W. K.; Chen, C. “A Highly Selective Vanadium Catalyst forBenzylic C–H Oxidation” Chem. Sci.2012, 3, 2240-2245.

9. Liu, W.-B.; Xia, J.-B.; You, S.-L. “Iridium-Catalyzed Asymmetirc Allylic Substitutions” Top. Organomet. Chem. 2012, 38, 155-208.

8. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L. “Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptanes and 3-Azabicyclo[3.2.0]heptanes viaIr-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction” Chem. Eur. J.2010, 16, 6442-6446.

 Highlighted in Synfacts 2010, 8, 909.

7. You, S.-L.; Xia, J.-B.; „„Palladium-Catalyzed Aryl–Aryl Bond Formation through Double C–H Activation‟‟ Top. Curr. Chem. 2010, 292, 165-194.

6. Xia, J.-B.; Jamison, T. F.; You, S.-L. „„Monodentate Chiral Ferrocenyl Ligands‟‟, in Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications, Dai, L.-X., Hou, X.-L., Eds, WILEY-VCH, Weinheim, 2010, pp. 55-71.

5. Xia, J.-B.; Zhuo, C.-X.; You, S.-L. “Synthesis of Cyclopropane-containing Building Blocks viaIr-Catalyzed Enantioselective Allylic Substitution Reaction” Chin. J. Chem. 2010, 28, 1525-1528.

4. Xia, J.-B.; You, S.-L. „„Synthesis of 3-Haloindolizines by Copper(II) Halides Mediated Direct Functionalization of Indolizines‟‟ Org. Lett. 2009, 11, 1187-1190.

3. Xia, J.-B.; Wang, X.-Q.; You, S.-L.„„Synthesis of Biindolizines through Highly Regioselective Palladium-Catalyzed C–H Functionalization‟‟ J. Org. Chem. 2009, 74, 456-458.

2. Wang, X.-Q.; Xia, J.-B.; Dai, X.-Y.; You, S.-L.„„Preparation of Ferrocenyl Imidazolines using Bis(triphenyl)oxodiphosphonium Trifluoromethansulfonate” Sci. China Chem.2009, 52,1331-1336.

1. Xia, J.-B.; You, S.-L.„„Carbon–CarbonBond Formation through Double sp2 C–H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives‟‟ Organometallics 2007, 26, 4869-4871